Naming Ionic Compounds with Transition Metals Introduction
this is an
introduction
tonaming
ionic
compounds
withtransition
metals
thetransition
metals
are the elements in this part of the periodic table and when we write the name for anionic
compound that containstransition
metals
those names usually have Roman numerals in the middle of them so in this video we'll learn how to take the formula for a compound that contains atransition
metal and how to write the name for it with Roman numerals and everything sotransition
metals
thetransition
metals
are the elements in this part of the periodic table here and I've written in some of the most common I'm also going to be talking about some of themetals
over here which aren't technicallytransition
metals
but they act a lot like them thesemetals
are unique because many of them are able to make multiple ions with different charges so iron Fe for example is able to make an Fe 2 plus ion but it's also able to make an Fe 3 plus ion okay this is different for themetals
sayover here that tend to always make ions with the same charge sodium for example is in this +1 column here and so when sodium isn't in an
ionic
compound it always makes an ion with a 1 plus charge magnesium here is in this 2 plus column so when it is in anionic
compound it makes a 2 plus ion but thetransition
metals
can make a wide variety of different ions with different charges some of them can even make 4 or 5 different ions each with a different charge so these different charges ontransition
metals
really come into play when we want to name a compound that contains atransition
al so here we have fecl3 and for the FE the iron we can't tell right away just by looking at this whether the Fe is Fe 2 plus or whether it's fe 3 plus right we have these two different types of ions that Fe can make now we can distinguish between these two ions by using Roman numerals to give them different names so the fe 2 plus ion we call that iron 2 with the Roman numeral for 2 inparentheses the fe 3 plus ion we call that iron 3 with a Roman numeral for 3 in parentheses and we'll use these ion names when we want name the whole compound so if the FE here turns out to be Fe 2 plus we'll call this compound iron 2 chloride and if this iron is iron 3 plus we will call the compound iron 3 chloride so in order to figure out whether we're talking about iron 2 chloride or iron 3 chloride here we got to do a little bit of math and work backwards to figure out which of
these two charges iron has in this particular compound let me show you how to do it so to find the charge of a
transition
metal we start by focusing on the ion with a charge that we do know that certain that's not going to change and for this that's going to be CL CL is in this column here on the periodic table so we know that in anionic
compound CL always makes an ion with a 1 minus charge okay so we've got CL 1 minus now how much total negative charge do we have here we have 3 CLs so that's going to be 1 2 3 and since we have 3 of them the total amount of negative charge is going to be 3 minus now in an
ionic
compound the negative charge always has to balance out with a positive charge so if we have 3 minus on this side we've got to have 3 plus on this side so what's the charge on iron well there is one iron ion in this compound which means that all of the positive charge has to be on this one island which means that its charge is Fe three-plus okay so oneion of fe 3 plus gives us three plus of charge which has to be balanced out by the three - over here which is distributed over the 3 CL minuses so that's how we figure out the charge on I and since this is iron three-plus the name for this compound is going to be iron 3 and then 4 CL when CL when chlorine becomes a negative ion we call it chloride the IDE usually gets added to the name of an element when it becomes a negative ion so chloride is what we call CL one - so iron 3 chloride is the
name of this compound we had to work backwards and figure out the charge of iron and then we can call it iron 3 so if you want to get really good at
naming
compounds
withtransition
metals
and using the Roman numerals and all that you just got to get a lot of practice so I've made another video that's just a whole bunch of practice problems onnaming
ionic
compounds
withtransition
metals
but before you check that out I want to talk about a couple of important things the first thing Iwant to talk about is when we use Roman numerals for
naming
and when we don't this confuses a lot of students ok so when do we use Roman numerals well we use Roman numerals when we'renaming
compounds
that containtransition
metals
so here are 3compounds
that containtransition
metals
and as you can see we use these Roman numerals and we use the Roman numerals because copper iron and vanadium aretransition
metals
which means that they can make multiple ions with different charges so wekind of need to pin down the specific ion that we're talking about in each one of these
compounds
right so we put this one here to say we're talking about copper 1 plus because copper could make other ions we're talking about iron 3 plus here we're talking about vanadium 4 plus because they could be a variety of different ions now on the other hand we don't use Roman numerals when we'renaming
compound that don't containtransition
metals
that contain for example themetals
over here take potassium iodide for example potassium K is in this column it's in the one plus column which means that in anionic
compound potassium always makes an ion with a 1 plus charge that's the only choice it can only be one plus so we don't need to put a Roman numeral in there to specify that it's 1 plus because that's the only choice that it could be calcium nitride over here calcium is in this 2 plus column and it can only make an ion with a two plus chargein an
ionic
compound so again we don't need a Roman numeral to say that because there's only one choice and that's 2 Plus now aluminium over here could only make a 3 plus ion so you don't need to use Roman numerals with aluminum either and I should point out that some of thesemetals
here that are not technicallytransition
metals
still can make ions with different charges so we have to use Roman numerals when we namecompounds
with tin and lead in them as well but here's abig point if you're
naming
compounds
with ions that can make different charges you always need the Roman numerals but don't put those Roman numerals in if you'renaming
compounds
withmetals
that can only make one charge not only is a waste of time to put those Roman numerals in but it's wrong you just shouldn't put them in there now we have to use this method of working backwards in order to namecompounds
that contain mosttransition
metals
and we also have to use thismethod to name
compounds
that containmetals
like tin or lead that are able to make more than one type of ion but there are two important exceptions and I need to tell you about these are silver AG and zinc Xion even though these two elements aretransition
metals
they're only able to make one type of ion so silver AG always makes a g1 plus it's always one plus and only one plus Zink Xion always makes an ion that is Z n 2 plus now that means that when we name compound to contain silveror zinc we don't have to use Roman numerals because we're only talking about one type of ion okay so a compound like this agcl you don't have to do any math at all you don't have to use a working backwards approach you just call it silver chloride ZN CL here super easy we just call that zinc chloride and since these elements always make ions with just one charge we don't have to use the Roman numerals when we're
naming
so it would be wrong to call this silver one chlorideor zinc 2 chloride here there's only one possible ion so we don't use the Roman numerals we only use the Roman numerals if we're trying to distinguish between multiple types of ions with different charges so that's an
introduction
to how we namecompounds
that havetransition
metals
and in the next video we'll do a whole bunch of practice problems so you can really get the hang of it this is one of the things that you just get better and better at with more practice so checkout that video you'll get super good at it really fast